Stainless Steel Austenitic Grades 304 316 by vastmaterial - Vastmaterial

Stainless Steel Austenitic Grades 304 316 by vastmaterial

Discover austenitic stainless steel grades 304 316 and more with corrosion resistance properties applications and supply options

Stainless Steel Austenitic Grade Overview

What is austenitic stainless steel?

When I talk about a stainless steel austenitic grade, I’m referring to the family of 300 series stainless steel (and a few high-alloy variants) with a stable face-centered cubic (FCC) crystal structure. This FCC structure, achieved mainly by adding nickel (and sometimes manganese and nitrogen), gives austenitic stainless steel its key traits:

  • Alta korrodorezisto
  • Bonega formebleco kaj fortikeco
  • Tre bona weldability

Common examples are 304 stainless steel (18/8 stainless steel) kaj 316 stainless steel, which you see everywhere from food equipment to chemical process lines.

Why is austenitic stainless “non-magnetic”?

In the fully annealed condition, an austenitic stainless steel grade is essentially cURL Too many subrequests. because the FCC structure does not support ferromagnetism the way body-centered cubic (BCC) or ferritic structures do. That’s why 304 and 316 are often called non-magnetic stainless steel.

However, after cold working (bending, forming, deep drawing, machining), some of the austenite can transform to martensite, which is magnetic. That’s why:

  • Annealed 304 sheet may be non-magnetic
  • The same sheet, after heavy forming or cold rolling, can show noticeable magnetism

This is normal and does ne mean the material is “fake” or low quality.

Why do austenitic grades dominate stainless steel production?

Austenitic stainless steels account for most of the stainless steel used worldwide cURL Too many subrequests.

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Austenitic stainless steel grades are my go‑to choice for most U.S. customers because they hit the sweet spot of corrosion resistance, formability, and weldability in one package.

Corrosion Resistance in Real-World Environments

Austenitic stainless steel (especially 304 stainless steel kaj 316 stainless steel) gives reliable protection in daily and aggressive conditions:

Medio Recommended Austenitic Grade Notoj
Indoor, dry, food contact                     304 / 304L (18/8 stainless steel)         Standard food-grade stainless
Outdoor, urban/industrial                     304L / 316L        Better resistance to pollution
Coastal, splash zone, de-icing salts                     316 / 316L (marine grade stainless steel)        Molybdenum alloyed stainless steel
Mild chemical processing                      316L / 904L        Higher alloy grades for harsh media
  • High chromium content builds a self-healing passive film.
  • Molybdenum, nitrogen, and copper in select austenitic grades boost pitting and crevice corrosion resistance.

Formability, Ductility, and Toughness

For complex, deep-drawn, or highly formed parts, austenitic stainless steel grades are extremely forgiving:

  • High elongation and ductility for deep drawing, bending, and spinning
  • Excellent toughness even at low temperatures
  • Ideal for sinks, exhaust systems, brackets, covers, and housings where shape is critical

Weldability and Easy Fabrication

If you’re welding in a U.S. fab shop, austenitic stainless steel is one of the easiest stainless families to work with:

  • Compatible with common processes: GTAW/TIG, GMAW/MIG, SMAW
  • Low-carbon 304L stainless steel kaj 316L rustorezista ŝtofo reduce sensitization and carbide precipitation
  • Good performance in cutting, forming, and machining with proper tooling

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cURL Too many subrequests.                                                 cURL Too many subrequests.      304, 316, 321
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304 stainless steel (18/8 stainless steel) cURL Too many subrequests.

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304L stainless steel cURL Too many subrequests.

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316 stainless steel is the go-to molybdenum alloyed stainless steel for chloride exposure:

  • Typical U.S. uses: marine hardware, chemical process lines, pulp and paper, coastal architecture, washdown areas, and some food and pharma piping.
  • Better pitting and crevice corrosion resistance than 304 in salt, brine, and chlorinated washdown.

316L rustorezista ŝtofo is the low carbon version:

  • Preferred for welded pipe, tube, and tanks in chemical, marine, and pharmaceutical service.
  • Lower risk of sensitization and carbide precipitation in the heat-affected zone.

321 Stabilized Stainless Grades (High Temperature)

321 stainless steel is a titanium stabilized stainless steel designed for high temperatures:

  • Titanium ties up carbon to reduce carbide precipitation at 800–1500°F.
  • Typical U.S. uses: exhaust manifolds, high-temp ducting, refinery and petrochemical equipment, and thermal processing lines.
  • Ideal when you need 304-type corrosion resistance but better resistance to sensitization at elevated temperatures.

310 High Temperature Stainless Steel

310 stainless steel is a cURL Too many subrequests. with higher chromium and nickel:

  • Built for continuous service at very high temperatures and oxidizing conditions.
  • Common U.S. uses: furnace parts, burners, heat treatment fixtures, kiln components, and radiant tubes.
  • Strong scale resistance, but you pay more per pound than 304/316, so it’s used where heat resistance truly matters.

904L and Other High Alloy Austenitic Stainless Steels

904L austenitic stainless steel is a super austenitic grade with high nickel, chromium, and molybdenum:

  • Excellent resistance to aggressive chlorides, sulfuric acid, and reducing environments.
  • Used in the U.S. for harsh chemical service, scrubbers, offshore equipment, and some high-end process systems where 316/316L is not enough.
  • Other high alloy austenitic grades (like 254 SMO and similar) push PREN corrosion resistance even further for extreme chloride and seawater service.
  • For very severe chloride or sour service, we may recommend alternatives like dupleksa rustorezista ŝtalo as covered in our duplex stainless steel product overview.

Global Grade Equivalents (AISI, UNS, EN, ISO)

Below is a quick reference for the main austenitic stainless steel grades in global systems:

Common Name AISI UNS EN (1.XXXX) Typical Use Note
304       304   S30400           1.4301                              cURL Too many subrequests.
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316      316   cURL Too many subrequests.       1.4401/1.4436                           cURL Too many subrequests.
316L     316L   cURL Too many subrequests.       1.4404/1.4432                         cURL Too many subrequests.
321     321   S32100       1.4541                       cURL Too many subrequests.
310S     310S   S31008      1.4845                        cURL Too many subrequests.
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  • Molibdeno (Mo)
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  • Kupro (Cu)
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These alloy tweaks are why austenitic stainless steel can compete with other specialty alloys like high‑temperature chromium–cobalt–molybdenum materials used in harsh service (chromium–cobalt–molybdenum high‑temperature alloys).

Carbon Content and “L” Low Carbon Grades

Carbon is small in quantity but big in impact:

  • Standard grades (e.g., 304, 316)
    • C typically up to 0.08%
    • Higher strength but more risk of carbide precipitation in the heat-affected zone during welding
  • “L” grades (304L stainless steel, 316L stainless steel)
    • C limited to about 0.03% max
    • Greatly reduces sensitization (chromium carbide formation at grain boundaries)
    • Safer choice for heavy welding, thicker sections, and corrosive service

In U.S. fabrication shops, cURL Too many subrequests. kaj 316L are standard picks when welds will see corrosive liquids, cleaning chemicals, or inspection under FDA/USDA guidelines.

Stabilizing Elements: Titanium and Niobium

Some austenitic stainless steel grades use stabilizers instead of (or in addition to) low carbon:

  • Titanio (Ti) – in 321 stainless steel
  • Niobium/Columbium (Nb/Cb) – in 347 stainless steel

These elements tie up carbon as stable carbides, which:

  • Reduce chromium carbide formation along grain boundaries
  • Improve resistance to intergranular corrosion je altaj temperaturoj
  • Make stabilized stainless grades a strong choice for high‑temperature and cyclic heating service

Composition, Weldability, and Sensitization Risk

The chemistry of an austenitic stainless steel grade directly drives how it welds and how it behaves after welding:

  • Higher carbon = higher sensitization risk
    • More likely to see intergranular corrosion along welds if not properly controlled
  • Low carbon (“L” grades) and stabilized grades
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  • 304 / 304L stainless steel
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  • It also means cutting tools must be sharp and well‑cooled to avoid excessive work hardening in the cut zone

If you’re comparing different alloys for strength and formability, it can help to look at how they harden with strain, similar to how we evaluate high‑performance alloys in our Gvidilo pri Inconel-alojoj.

Impact Toughness and Cryogenic Behavior

A key reason austenitic stainless steel is used in LNG, aerospace, and medical equipment is its cURL Too many subrequests.:

  • Toughness stays high even at cryogenic temperatures (down to liquid nitrogen or LNG conditions)
  • No brittle transition like carbon steel—parts stay ductile and safe under impact loading
  • Ideal for tanks, piping, and pressure components that see low‑temperature service

Effect of Cold Working on Strength and Performance

Cold work has a major impact on mechanical performance:

  • Strength up: yield and tensile strength can increase 2–3× from heavy cold reduction
  • Ductility down: elongation drops as strength rises, so very high cold work reduces formability
  • Slight magnetism: heavily cold‑worked non‑magnetic stainless steel like 304 can become slightly magnetic
  • Residual stress: may require stress‑relief annealing to reduce distortion and improve fatigue life

In practice, we tailor the level of cold work to hit the right balance of strength, toughness, and forming behavior for each application, whether it’s thin stainless steel sheet and plate or high‑strength bar and fittings.

Physical Properties of Austenitic Stainless Steel

Density and Weight vs Carbon Steel

Austenitic stainless steel has a density of about 7.9–8.0 g/cm³, slightly higher than typical carbon steel (~7.85 g/cm³).
En praktiko:

  • Weight per foot of plate, bar, and pipe is very similar to carbon steel
  • You don’t choose austenitic stainless for weight savings—you choose it for corrosion resistance and durability

Thermal Expansion and Welding Impact

Austenitic stainless has a higher coefficient of thermal expansion than carbon steel, especially from room temperature up to 1000°F. That means:

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Austenitic stainless steel can face stress corrosion cracking in hot chloride conditions (like hot brine, some refinery and chemical processes). To reduce SCC risk:

  • Avoid high residual stresses (use proper design and stress relief where possible).
  • Use low carbon stainless steel grades like 304L stainless steel and 316L stainless steel for better weld performance.
  • Upgrade to higher-alloy or duplex stainless when chloride + temperature + stress are all high.

Intergranular Corrosion and Sensitization

Sensitization happens when austenitic stainless is held in the 800–1500°F (425–815°C) range, causing chromium carbide precipitation at grain boundaries and localized attack:

  • Uzu L grades (304L, 316L) to reduce sensitization after welding.
  • Uzu stabilized stainless grades like 321 (titanium stabilized stainless steel) or 347 (niobium stabilized) for repeated high-temperature exposure.
  • Follow good welding and post-weld cleaning to keep the passive film strong.

Using PREN to Compare Austenitic Grades

To compare corrosion resistant steel options fast, I look at PREN (Pitting Resistance Equivalent Number). Higher PREN = better pitting/crevice corrosion resistance in chlorides. Rough guide for austenitic stainless steel:

  • 304: PREN ~18–19
  • 316: PREN ~23–24 (better marine and chemical resistance)
  • 904L and other high alloy austenitic stainless: PREN 30+ for aggressive chloride and chemical service

When you’re picking a stainless steel austenitic grade for U.S. coastal, food-grade stainless steel, or chemical plant use, I always match the PREN and alloy level to the real chloride and temperature conditions—not just the purchase price.

Applications of Austenitic Stainless Steel Grades

Austenitic stainless steel grades are my go-to materials when I need a mix of corrosion resistance, cleanability, and easy fabrication. In the U.S. market, 304 stainless steel, 316 stainless steel, and other 300 series stainless steel grades show up in almost every major industry.

Food, Dairy, and Beverage Equipment

For food-grade stainless steel, 304 and 316 austenitic stainless steel are standard. They’re easy to clean, resist staining, and meet strict hygiene expectations for:

  • Food processing lines and mixing tanks
  • Dairy equipment, piping, and fittings
  • Brewery, winery, and beverage systems

When I supply equipment for ekipaĵa fabrikado in these sectors, I rely on austenitic grades to keep surfaces smooth, sanitary, and compliant with U.S. food safety expectations.

Chemical and Petrochemical Equipment

In chemical plants and refineries, corrosion resistant steel is non‑negotiable. 316/316L stainless steel and molybdenum alloyed stainless steel like 904L handle:

  • Chlorides, mild acids, and process chemicals
  • Reactors, heat exchangers, and storage tanks
  • Stainless steel pipe and tube systems

Here, the right austenitic stainless steel grade cuts downtime and extends service life.

Pharmaceutical and Biotech Installations

Pharma and biotech facilities demand ultra-clean, fully weldable stainless steel:

  • High-purity piping, manifolds, and skids
  • Vessels, bioreactors, and cleanroom hardware

Non-magnetic stainless steel with smooth finishes and excellent weldability helps meet validation and cleaning protocols.

Architecture and Construction

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  • Motoro kaj elirejaj komponantoj

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2B                                                        Cold-rolled, smooth matte                    General fabrication, industrial
BA                                                        Bright annealed, reflective                   Appliances, decorative fronts
No.4                                                        Brushed, hairline                    Food equipment, architectural
Custom Polish                                                       #6–#8 mirror, directional                     High-end architectural, sanitary

Standard Size Range (Stock Program)

Typical stock ranges for austenitic stainless steel:

Sheet & Plate (inch)

  • Thickness: 0.024″ – 2.00″
  • Larĝo: 36″, 48″, 60″, 72″
  • Longeco: 96″, 120″, 144″ (plus cut-to-length)

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  • Round: 3/16″ – 12″ dia
  • Flat: 1/8″ – 6″ thick, ĝis 12″ wide

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  • NPS: 1/4″ – 24″ (welded and seamless)
  • Tubing: 1/8″ – 8″ OD, standard and heavy wall

(Custom non-standard sizes and precision blanks are available on request.)

Standards and Specifications (ASTM, ASME, EN, ISO)

I supply austenitic stainless steel grades to major international standards, including:

  • ASTM: A240 (plate/sheet), A276 (bar), A312 (pipe), A269/A249 (tube)
  • ASME: Section II materials for pressure equipment
  • EN / ISO: EN 10088, EN 10272, EN 10216 / 10217, ISO material numbers

Material is identified by AISI, UNS, kaj EN designations so you can match your drawings and project specs easily.

Tolerances, Certification, and Testing

For U.S. manufacturing and EPC projects, I keep documentation tight and predictable:

  • Dimensiaj Toleradoj
    • To ASTM/EN standards or tighter upon request
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    • PMI (Pozitiva Materiala Identigo)
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  • 304 / 304L → ER308L / E308L.
  • 316 / 316L → ER316L / E316L (molybdenum alloyed stainless for better chloride resistance).
  • 321 → ER347 (niobium stabilized).
  • 310 → ER310 for high‑temperature service.
  • 904L → high‑alloy austenitic fillers like ER385.

Always match the filler to the service conditions (corrosion, temperature, and code requirements).


Avoiding Sensitization and Carbide Precipitation

To keep corrosion resistance high, you must control sensitization in welds.

  • Prefer low carbon stainless steel grades (304L, 316L) for welded assemblies.
  • For higher‑temperature service, use stabilized stainless grades (321 Ti‑stabilized, 347 Nb‑stabilized).
  • Minimize heat input and avoid long dwell in 800–1500°F (425–815°C), where chromium carbides form.
  • Keep interpass temperatures under control and avoid repeated reheating of the same weld area.
  • If severe sensitization is suspected and design allows, solution anneal and rapid quench.

Post‑Weld Cleaning, Pickling, and Passivation

Weld cleanup directly impacts corrosion performance, especially for “food grade stainless steel” and sanitary service.

  • Mechanically remove weld spatter, heat tint, and slag by grinding or brushing with stainless-only tools.
  • Use chemical pickling (gels or baths) where welding burned the surface heavily and created oxides.
  • Finish with passivado (nitric or citric solutions) to restore a strong chromium‑rich passive film.
  • For projects with high cosmetic or hygiene demands, we also apply dedicated surface treatment and polishing services to reach No.4, BA, or mirror finishes.

Heat Treatment and Annealing of Austenitic Grades

Austenitic stainless steel is not hardened by heat treatment, but annealing is key to restoring properties.

  • Solution annealing: typically 1850–2050°F (1010–1120°C), followed by quick water or air quench to dissolve carbides and reset the corrosion resistance.
  • Use solution anneal after heavy cold work or severe forming to restore ductility.
  • Avoid holding in the sensitization range (800–1500°F / 425–815°C) for long periods.
  • Stress relieving is possible, but must be done at lower temperatures and short times to avoid sensitization.

Handled correctly, austenitic stainless steel remains weldable, formable, and corrosion‑resistant through the full fabrication cycle.

Selecting the Right Austenitic Stainless Steel Grade

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Choosing the right stainless steel austenitic grade comes down to where it’s used, how harsh the environment is, and how you’ll fabricate it. I always look at these five points first.

Match Grade to Environment & Corrosion Risk

Use the environment to narrow down your austenitic stainless steel options:

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  • 304 stainless steel (18/8 stainless steel)
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  • 316 stainless steel
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  • Por higher strength without heat treatment:
    • Use cold-worked austenitic stainless steels; they work harden fast.
    • Be ready for more challenging forming and machining.
  • Por critical weldable stainless steel:
    • Stick with 304L, 316L, or 321 with matching filler metals.
    • Control heat input and follow proper post-weld cleaning and passivation.

I always balance:
Can we form it easily? Can we weld it safely? Does it meet the minimum strength and corrosion requirements?

Total Cost of Ownership vs Initial Material Cost

In the U.S. market, it’s common to focus on price per pound, but with austenitic stainless steel you win or lose on lifecycle cost:

  • A cheaper grade like 304 can cost more long-term if:
    • It pits or fails in a chloride environment.
    • You have frequent downtime, cleaning, or replacement.
  • A higher grade like 316L or 904L can be the better deal when:
    • The process is critical (food, pharma, chemical).
    • Access for repairs is difficult or shutdowns are expensive.
    • Regulatory and hygiene standards demand high reliability.

I always look at tutan koston de posedo: material price, fabrication cost, expected life, maintenance, risk of failure, and compliance. For most American plants, that’s the difference between “acceptable on paper” and “profitable in real operation” when choosing the right austenitic stainless steel grade.

FAQs on Austenitic Stainless Steel Grades

1. What’s the difference between 304 stainless steel and 316 stainless steel?

Trajto 304 Stainless Steel (18/8) 316 Stainless Steel (Marine Grade)
Main alloying elements                                 ~18% Cr, 8–10.5% Ni                             ~16–18% Cr, 10–14% Ni, 2–3% Mo
Koroda rezisto                               Very good for everyday use                       Better in chlorides, salts, and chemicals
Tipaj uzoj                               Appliances, kitchen, tanks, architecture                       Marine, chemical, pharma, coastal equipment
Kosto                                                    Pli malalta                                           Pli alta
  • 304 stainless steel works great for most indoor, dry, and mildly corrosive environments.
  • 316 stainless steel is my go‑to when there’s salt, chlorides, or harsh chemicals involved.

2. When should I choose 304L vs 316L low carbon grades?

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    • 304 / 304L stainless steel
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cURL Too many subrequests.                                                                                                  316 / 316

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